Rare igneous rocks that contain more than 50
percent carbonate. Some carbonatites are calcitic (sovite)
whereas magnesio-carbonatites (rauhaugites) have dolomite
as the primary carbonate mineral. Ferro-carbonatites have
calcium-magnesium and iron carbonate minerals. There are
more than 350 carbonatite intrusions and volcanoes recognized
on Earth, with many of these in the East African rift
system. Northern Tanzania hosts the world’s most dense carbonatite
province, where active eruptions from centers such
as Ol Doninyo Lengai produce short-lived bizarre flows with
twisted spires, swirls, and oozes made of the extremely fluid
carbonatite. The carbonatite lavas flow with a viscosity similar
to that of olive oil, the lowest viscosity known for any
magma on Earth. Other carbonatites are associated with kimberlites
and alkalic rocks and are all located on continental
crust. Most carbonatites are very small, being less than 1
square kilometer in area, with the largest known complex
being 7.5 square miles (20 km2). They range in age from Proterozoic
(2.0 billion years old) to the present with most being
younger than 150 million years old.
The chemistry of carbonatites shows that they formed by
magmatic processes in the mantle. They have high concentrations
of rare elements such as phosphorous and sodium and
compositionally grade into kimberlites. Intrusion of both
kimberlites and carbonatites causes intense alteration of surrounding
country rocks, characterized by the addition of
sodium and potassium.
Carbonatites are thought to form by small amounts of
partial melting in the upper mantle, although there has been a
large amount of controversy about the origin of this volumetrically
minor group of igneous rocks. Some models suggested
that carbonatites were formed by the remobilization of sedimentary
limestones by heat from nearby silicic intrusions, but
these ideas have been largely discredited. Carbonatite magmatism
tends to occur repeatedly, but not continuously, for
hundreds of millions or even billions of years in the same
location, suggesting that some unusual aspect of the mantle
in these areas leads to the formation of magmas with such
rare compositions. It has been noted that carbonatite magmatism
in the African plate seems to coincide with distant plate
collisions or periods of increased global magmatic activity,
although the cause of these apparent trends is unknown.
See also DIVERGENT OR EXTENSIONAL BOUNDARIES;
IGNEOUS ROCKS; RIFTS.














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