Sediments deposited directly by precipitation
from solution, evaporation, or from deposition of
insoluble precipitates. They differ from the other main type of
sediments and sedimentary rocks, known as clastic sediments
and rocks, which are made of particles broken from another
source, transported, and deposited as the new sediment.
Common types of chemical sediments include limestones,
dolostones, evaporites, chert, phosphates, and ironstones.
Some chemical sediments are produced by a combination of
biochemical processes, especially varieties of limestone, dolostone,
some types of phosphates, and banded iron formations.
Limestones and dolostones are carbonate rocks composed
primarily of calcite and dolomite and produced by a
combination of accumulation of dead organisms above the
level that calcium carbonate is saturated in seawater (the calcium
carbonate compensation depth), and by biochemical
and chemical reactions that precipitate carbonate from solution.
Evaporites, commonly gypsum (CaSO4 • 2 H2O), anhydrite
(CaSO4), and halite (NaCl), form most commonly by
the evaporation of seawater or shallow restricted lake basins
in arid environments, known as playas. In some of these
examples, rainwater flows through older rock deposits, dissolving
the evaporite minerals from the older rocks, then
reprecipitating the minerals as new evaporites in restricted
basins. Chert is a rock composed of nearly pure silica, consisting
of microcrystalline or cryptocrystalline quartz. Chert
may form from the inorganic or biologic precipitation from
seawater. Phosphates commonly form nodules on the
seafloor, as layered sediments in shallow water environments,
and as guano accumulations, especially from sea birds. Manganese
forms nodules on the seafloor, and some are associated
with black smoker types of submarine hydrothermal vents.
Others are located in shallow water environments. Ironstones
and banded iron formations are iron-rich sedimentary rocks
that are especially common in Precambrian rocks and may
reflect different levels of atmospheric oxygen and iron redox
state in the early oceans. These unique formations contain the
world’s largest reserves of iron ore, but the lack of a modern
analog environment makes understanding their origin somewhat
enigmatic.
See also BANDED IRON FORMATION; BLACK SMOKER
CHIMNEYS; CARBONATE; CHERT.
 






 















 
  
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